I don't know But it May Well work. This kind of Question I ask the Verizon Store where I Bought my Samsung Android Phone. I say it may work because the 16 GB & 32 are likely Not a lot different in size; But I only know enuff about smart phones to know they are smarter than me. I have put a larger Memory Card in a Previous Cell phone that was not a smart phone, But I Got it Put in at the Place where I bought that call ( AT&T Store ). I'm 72 yrs old & You need a Techie that is Likely 25 or so ! 

As much as you can get, I think they go all the way up to 132 gigabytes but 32 should be sufficient 

It will take some time, videos or memory heavy and you need to wait while the data transfers I generally put it together and let it sit for a couple hours just to make sure 

Yes! Install the memory card in the second sim slot.